An old thread but here's some useful tips that work for me.

1. Well rested
2. Either very hydrated or deydraded. No in between
3. High sodium
4. Warmer body temperature
5. 100% Beet juice (no concentrate) 10-20 min before
   before activity or pump. Excellent Nitric oxide!
6. Low bodyfat.

diet,arginine and supplements of nitric oxide etc,training with sperset or set with 15-20reps with short rest as 30sec/45sec.you must feel your muscle pumping.i used aspirin in my past...every vasodilator can help(as aspirin,caffeine.....)
but who downvoted him? for me +1to compensate

I've read that increases in blood pressure during exercise helps pump the veins bigger and enlarging them permanently. I'm not the most vascular, but the leaner I got the more vascular I was obviously. Also, I squeeze dumbbells with my fist as hard as I can with any dumbbell exercises and it has pumped my veins up A LOT.

Avoid salt like the guy below said. I have been cutting and had next to no salt for months, i've been getting more and more lean with a vascular look. However on thursday I went out for a Thai Curry and it was LOADED with salt, really high salted foods all over. The two days since I feel i've put around 4/5 lbs of water weight on. Im not worried about the fat, just the fact I feel really bloated now, but i've had no salt since and its starting to shread again. The diet is massively important especially low sodium, eat clean.

Watch your salt intake. Try to limit to as nest to zero as possible.

Diet. ALso try having low water levels under your skin. Drink like 2 gallons of water a day too. Eat lots of vegetables and drink apple cider vinegar too.

DO lots of heavy dumbell exercises and do high reps heavy weight and really squeeze to get the blood rushing through. Drinking 1-MR pre workout helps expand the veins too i noticed during your lift

High rep work also, but the big one is get the bf% down then control water for the final look!

Arginine and licorice root